台湾中央大學教務長
李光華 教授 Kwang-Hwa Lii
個人
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李光華 教授 Kwang-Hwa Lii
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電話:
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#分機 (研究室)。(教務長辦公室)
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E-mail:
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簡歷
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台灣師範大學化學系學士 (1976)
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美國Iowa State University無機化學博士 (1985)
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美國Exxon Research and Engineering Co.博士後研究 (1986)
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台湾中央研究院化學研究所副研究員 (1987-1990)
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台湾中央研究院化學研究所研究員 (1990-1999)
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台湾中央研究院化學研究所合聘研究員 (1999-)
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台湾中央大學化學系教授(1998-)
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台湾中央大學化學系系主任 (1998-2003)
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台湾中央大學理學院院長(2004-2006)
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台湾中央大學教務長(2006-)
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台湾國科會傑出研究獎(1991、1998、2003)
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ISI引用經典論文獎(2001)
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台湾教育部學術獎(2004)
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台湾教育部國家講座(2007)
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台湾中央大學講座教授(2008-)
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Solid State Sciences編輯諮詢委員(1998-)
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Journal of Solid State Chemistry編輯諮詢委員(2000-)
現職及職稱
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台湾國立中央大學化學系教授
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台湾國立中央大學教務長
研究領域:固態無機化學
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高溫高壓水熱合成金屬磷酸鹽、砷酸鹽與矽酸鹽。合成含有過渡金屬或13族元素的新穎微孔固體,置重點於有機模板金屬磷酸鹽,特別是含手性有機胺的化合物。此外也合成包含無機、有機配位基的三維架構化合物。
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合成嵌入具有觸媒活性金屬錯合物的微孔金屬磷酸鹽。
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以粉末與單晶X光繞射、電子顯微鏡、梅思堡光譜、熱分析、磁性與固態核磁共振等方法鑑定晶體結構。
近五年著作 (2005-2009)
(1) |
Chen, C.-S.; Kao, H.-M; Lii, K.-H., “K5(UO2)2[Si4O12(OH)]: a New Uranyl Silicate Containing Chains of Four Silicate Tetrahedra Linked by SiO···HOSi Hydrogen Bonds”, Inorg. Chem. 2005, 44, 935-940. |
(2) |
Hung, L.-I; Wang, S.-L.; Chen, C.-Y.; Chang, B.-C.; Lii, K.-H., “Rb3In(H2O)Si5O13: A Novel Indium Silicate with CdSO4-Topological-Type Structure”, Inorg. Chem. 2005, 44, 2992-2994. |
(3) |
Lo, F.-R.; Lii, K.-H., “High-Temperature, High-Pressure Hydrothermal Synthesis and Characterization of a New Framework Stannosilicate: Cs2SnSi3O9”,J. Solid State Chem. 2005, 178, 1017-1022. |
(4) |
Chen, C.-S.; Chiang, R.-K.; Kao, H.-M.; Lii, K.-H., “High-Temperature, High-Pressure Hydrothermal Synthesis, Crystal Structure, and Solid-State NMR Spectroscopy of Cs2(UO2)(Si2O6) and Variable-Temperature Powder X-ray Diffraction Study of the Hydrate Phase Cs2(UO2)(Si2O6)·0.5H2O”, Inorg. Chem. 2005, 44, 3914-3918. |
(5) |
Chen, C.-S.; Lee, S.-F.; Lii, K.-H., “K(UO)Si2O6: A Pentavalent-Uranium Silicate”,J. Am. Chem. Soc. 2005, 127, 12208-12209. |
(6) |
Wang, C.-M.; Liao, C.-H.; Kao, H.-M.; Lii, K.-H., “Hydrothermal Synthesis and Characterization of [(UO2)2F8(H2O)2Zn2(4,4’-bpy)2]·(4,4’-bpy), A Mixed-Metal Uranyl Aquofluoride with a Pillared Layer Structure”, Inorg. Chem. 2005, 44, 6294-6298. |
(7) |
Huang, M.-Y.; Chen, Y.-H.; Chang, B.-C.; Lii, K.-H., “High-Temperature, High-Pressure Hydrothermal Synthesis, Crystal Structure, and Luminescence Properties of Cs3EuSi6O15, a New Europium(III) Silicate with a Three-Dimensional Framework Structure”, Chem. Mater. 2005, 17, 5743-5747. |
(8) |
Chang, W.-J.; Chang, P.-C.; Kao, H.-M.; Lii, K.-H., “Synthesis, Structural Characterization, and Solid-State NMR Spectroscopy of [Ga(phen)(H1.5PO4)2]·H2O and [Ga(phen)(HPO4)(H2PO4)]·1.5H2O (phen = 1,10-phenanthroline), Two Organic-Inorganic Hybrid Compounds with 1-D Chain Structures”, J. Solid State Chem. 2005, 178, 3709-3715. |
(9) |
Liao, C.-H.; Chang, P.-C.; Kao, H.-M.; Lii, K.-H., “Synthesis, Crystal Structure, and Solid-State NMR Spectroscopy of a Salt-Inclusion Stannosilicate: [Na3F][SnSi3O9]”, Inorg. Chem. 2005, 44, 9335-9339. |
(10) |
Chang, W.-J.; Jiang, Y.-C.; Wang, S.-L.; Lii, K.-H., “Synthesis and Structural Characterization of Two Polymorphs of Fe(2,2’-byp)(HPO4)(H2PO4)”, J. Solid State Chem. 2006, 179, 3059-3064. |
(11) |
Tsao, C.-P.; Sheu, C.-Y.; Nguyen, N.; Lii, K.-H., “Ionothermal Synthesis of Metal Oxalatophosphonates with a Three-Dimensional Framework Structure: Na2M3(C2O4)3(CH3PO3H)2 (M = FeII and MnII)”,Inorg. Chem. 2006, 45, 6361-6364. |
(12) |
Chang, W.-J.; Jiang, Y.-C.; Wang, S.-L.; Lii, K.-H., “Hydrothermal Synthesis of a Three-Dimensional Organic-Inorganic Hybrid Network Formed by Poly(oxomolybdophosphate) Anions and Nickel Coordination Cations”, Inorg. Chem. 2006, 45, 6586-6588. |
(13) |
Huang, L.-I; Wang, S.-L.; Chen, Y.-H.; Lii, K.-H., “Rb6(InCo)2(Si9O26): A Mixed-Metal Silicate Containing 20-Membered-Ring Silicate Single Layers with a Very Low Si:O Ratio“,Inorg. Chem. 2006, 45, 2100-2103. |
(14) |
Sheu, C.-Y.; Lee, S.-F.; Lii, K.-H., “Ionic Liquid of Choline Chloride/Malonic Acid as a Solvent in the Synthesis of Open-Framework Iron Oxalatophosphates”, Inorg. Chem. 2006,45, 1891-1893. |
(15) |
Wang, C.-M.; Liao, C.-H.; Chen, P.-L.; Lii, K.-H., “UF3(H2O)(C2O4)0.5: A Fluorooxalate of Tetravalent Uranium with a Three-Dimensional Framework Structure”, Inorg. Chem. 2006, 45, 1436-1438. |
(16) |
Hung, L.-I; Wang, S.-L.; Kao, H.-M.; Lii, K.-H., “Flux Synthesis, Crystal Structures, and Solid-State NMR Spectroscopy of Two Indium Silicates Containing Varied In-O Coordination Geometries”, Inorg. Chem. 2007, 46, 3301-3305. |
(17) |
Chiang, P.-Y.; Lin, T.-W.; Dai, J.-H.; Chang, B.-C.; Lii, K.-H., “Flux Synthesis, Crystal Structure, and Luminescence Properties of a New Europium Fluoride-Silicate: K5Eu2FSi4O13”, Inorg. Chem. 2007, 46, 3619-3622. |
(18) |
Lai, Y.-L.; Lii, K.-H.; Wang, S.-L., “26-Ring-Channel Structure Constructed from Bimetal Phosphite Helical Chains”, J. Am. Chem. Soc. 2007, 129, 5350-5351. |
(19) |
Huang, Y.-L.; Huang, M.-Y.; Chang, T.-H.; Chang, B.-C.; Lii, K.-H., “Synthesis, Structural Characterization and Luminescence Properties of Lanthanide Oxalatophosphonates: Na[M3(H2O)4(C2O4)4(CH3PO3)]·2H2O (M = Nd and Pr)”, Chem. Mater. 2007, 19, 3232-3237. |
(20) |
Wang, C.-M.; Wu, Y.-Y.; Chen, P.-L.; Lii, K.-H., “Organically Templated Uranium(IV) Fluorooxalates with Layer Structures: (H4TREN)[U2F6(C2O4)3]·4H2O (TREN = tris(2-aminoethyl)amine) and (H4APPIP)[U2F6(C2O4)3]·4H2O (APPIP = 1,4-bis(3-aminopropyl)piperazine)”, Dalton Trans. 2007, 1034-1037. |
(21) |
Tang, M.-F.; Liu, Y.-H.; Chang, P.-C.; Liao, Y.-C.; Kao, H.-M.; Lii, K.-H., “Ionothermal Synthesis, Crystal Structure and Solid-State NMR Spectroscopy of a New Organically Templated Gallium Oxalatophosphate: (H2TMPD)0.5[Ga3(C2O4)0.5(PO4)3] (TMPD = N,N,N’,N’-tetramethyl-1,3-propanediamine)”, Dalton Trans. 2007, 4523-4528. |
(22) |
Wang, C.-M.; Wu, Y.-Y.; Chang, Y.-W.; Lii, K.-H., “Luminescent Lanthanide Oxalatophosphites with a 3D Framework Structure: [Ln(H2O)(C2O4)0.5(HPO3)]·H2O (Ln = Pr, Nd, and Sm-Lu)”, Chem. Mater. 2008, 20, 2857-2859. |
(23) |
Lee, C.-S.; Liao, Y.-C.; Hsu, J.-T.; Wang, S.-L.; Lii, K.-H., “Rb2REGaSi4O12 (RE = Y, Eu, Gd, Tb): Luminescent Mixed-Anion Double Layer Silicates Containing Chains of Edge-Sharing REO7 Pentagonal Bipyramids”, Inorg. Chem. 2008, 47, 1910-1912. |
(24) |
Chen, P.-L.; Chiang, P.-Y.; Yeh, H.-C.; Chang, B.-C.; Lii, K.-H., “Synthesis, Crystal Structure, Magnetic and Luminescence Properties of KEuGe2O6: A Europium Cyclogermanate Containing Infinite Chains of Edge-Sharing Eu-O Polyhedra”, Dalton Trans. 2008, 1721-1726. |
(25) |
Lai, Y.-L.; Chiang, R.-K.; Lii, K.-H.; Wang, S.-L., “The First Organically Templated Tetravalent Uranium Phosphates with Dimer-Structured Topologies”, Chem. Mater. 2008, 20, 523-530. |
(26) |
Lin, C.-H.; Chen, C.-S.; Shiryaev, A. A.; Zubavichus, Ya. V.; Lii, K.-H., “K3(U3O6)(Si2O7) and Rb3(U3O6)(Ge2O7): A Pentavalent-Uranium Silicate and Germanate”, Inorg. Chem. 2008, 47, 4445-4447. |
(27) |
Tang, M.-F.; Chiang, P.-Y.; Su, Y.-H.; Jung, Y.-C.; Hou, G.-Y.; Chang, B.-C.; Lii, K.-H., “Flux Synthesis, Crystal Structures, and Luminescence Properties of Salt-Inclusion Lanthanide Silicates: [K9F2][Ln3Si12O32] (Ln = Sm, Eu, Gd)”, Inorg. Chem. 2008, 47, 8985-8989. |
(28) |
Lin, C.-H.; Lii, K.-H., “A3(U2O4)(Ge2O7) (A = Rb, Cs): Mixed-Valence Uranium(V,VI) Germanates”, Angew. Chem. Int. Ed. 2008, 47, 8711-8713. |
(29) |
Tsi, J.-M.; Tu, P.-T.; Chan, T.-S.; Lii, K.-H., ”Synthesis and Characterization of Open-Framework Niobium Silicates: Rb2(Nb2O4)(Si2O6)·H2O and the Dehydrated Phase Rb2(Nb2O4)(Si2O6)”, Inorg. Chem. 2008, 47, 11223-11227. |
(30) |
Wang, C.-M.; Wu, Y.-Y.; Hou, C.-H.; Chen, C.-C.; Lii, K.-H., “Synthesis, Characterization, and Properties of Organically Templated Lanthanide Oxalatophosphates with a Three-Dimensional Honeycomb Structure: (H4APPIP)[Ln3(C2O4)5.5(H2PO4)2]·5H2O (Ln = Er-Lu, APPIP = 1,4-bis(3-amino-propyl)piperazine)”, Inorg. Chem. 2009, 48, 1519-1523. |
(31) |
Lin, C.-H.; Chiang, R.-K.; Lii, K.-H., “Synthesis of Thermally Stable Extra-Large Pore Crystalline Materials: A Uranyl Germanate with 12-Ring Channels”, J. Am. Chem. Soc. 2009, 131, 2068-2069. |
(32) |
Wang, C.-M.; Lii, K.-H., “Synthesis of Novel Organic-Inorganic Hybrid Compounds: Lanthanide Phosphites Incorporating Squarate Ligands”, Inorg. Chem. 2009, 48, 6335-6337. |
(33) |
Lee, C.-S.; Wang, S.-L.; Chen, Y.-H.; Lii, K.-H., “Flux Synthesis of Salt-Inclusion Uranyl Silicates: [K3Cs4F][(UO2)3(Si2O7)2] and [NaRb6F][(UO2)3(Si2O7)2]”, Inorg. Chem. 2009, in press. |
(34) |
Lee, C.-S.; Wang, S.-L.; Lii, K.-H.,“Cs2K(UO)2Si4O12: A Mixed-Valence Uranium(IV,V) Silicate”, J. Am. Chem. Soc. 2009, in press |
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